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Try close grip bench presses for the inner pecs. As for upper pecs continue to do incline db presses... maybe you can add incline db flyes and maybe even incline close grip barbell presses.

Why don't you try...
20, 15, 12, 10, 8

Pushdowns, dumbbell overhead extensions (one hand or both), kickbacks, dips.

Dumbbell Rows, but not pulling straight up and down. Try to pull the dumbbell back a little and squeeze the lower lats.

Skip, how many calories do you consume?

I never do dips.

John, what does your back and biceps workout look like?

Bob,
what do you think when you see skinny guys walking in tanktops with imaginary lat syndrome thinking they're all bada$$?

Bob,
in your offseason how many calories do you consume?
How many calories do you consume in the inseason.

Try DB front raises, close grip bench press, skullcrushers, tricep pushdowns, etc.

This is what I do:

Biceps

barbell curls, 4 - 5 sets, 5 - 12 reps

preacher curls, 3 - 4 sets, 6 - 12 reps

alt. db curls, 4 - 5 sets, 6 - 12 reps

I would say I'm a true ectomorph.

The OP said his wife's lower thigh, where it inserts into the knee, needs the most work. Squats will do very little to improve that area, as it will just add sheer mass to the outer sweep, not the...

Leg extensions, leg extensions, leg extensions.

I notice I can get a really good squeeze/pump in the chest whenever I:

take a narrow ( 10 - 12 inch) grip, like a close grip bench press

and/or

tuck my elbows in

Not sure, maybe around 4000 - 5000 calories.

On average I eat slightly above 3000 calories.

Isn't yours the exact same as mine?

How about this OP:

M Chest/Tris

TU Back/Bis

W Rest

But would I be able to retain muscle mass and become really cut?

If I drank like 6 whey protein shakes a day (and maybe a little bit of fruit/carbs on the side)? Would I get extremely cut?

For Ronnie's genetics, I would start over at 90 pounds.